You can listen to lifeflow all you want, as you can play it over speakers whilst you're doing stuff (though I think it's not recommended whilst driving, operating machinery etc. the usual precautions).
As for meditating whilst using lifeflow, it's possible to over-meditate, especially if you're new to meditation, and this can cause what is called "overwhelm" whereby a lot of issues/emotions etc. come up and, unless you're prepared, can be difficult to deal with all in one go.
Hugs
Giles
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